What is more beneficial, a GTX 770 with 24GB of RAM, or 32 GB of RAM and a lower end GPU. This is all purely for video editing with Premiere Pro and some After Effects, any help would be appreciated. Also, this will all be paired with an overclocked FX-8370E.
The GTX 770 will have no effect on either application. As noted in the links, nVidia has GPUs that After Effects CS6 and Premiere Pro CS6 can take advantage of, but they're all Quadro Series cards. So, in your case, getting more RAM will help you a whole lot better than the GPU.