It appears there's a piece of ransomware actually called "Bit Locker", so the normally Almighty Google isn't quite so useful.
Most of the attacks I see in the Wikipedia page linked are focused on evil-maid style attacks.
The real question with encryption, IMHO, is always 'who handles the keys'? If you're storing the keys on the PC (even if you're only mounting it during the backup), then it would be pretty easy for ransomware to auto-mount any drives found. If a person is typing them in at 5PM every day, why not have them plug the drive in? What happens if the ransomware hits while the backup drive is mounted?
That said, from my understanding, it's very rarely the actual file server that's hit. A user gets hit, then it encrypts files on any shares it has write access to. If you lock down the users' permissions and ensure no-one can write to the backups except the daemon, this prevents damage unless your server somehow executes a file it's meant to be storing.