PEx is great!
So you're building some great small 2-way speakers. Why do you need 8 ohms? Most amps can handle a minimum impedance of 4 ohms. You get more power by loading an amp near it's min. imp. rating, but it may operate warm. If there's no issue with the amp, I'd accept 4 ohms as your system impedance. You choose the crossover components for the impedance/ DCR of the drivers. So stick with values for a 4 ohm system in this case. You MUST also consider the sensitivity ratings of drivers you choose and may need to 'pad' the tweeter, because there's a big difference between the 86.8db (woofer) and 95 db (tweeter) 2.83V/1m values. You will not be happy without padding the tweeter down to match the woofer. Also, the tweeter's power rating is 30 watts. I'm not sure if that's tested with a 1st or 2nd order curve, but you may get better tweeter power handling and protection by shifting the crossover point higher, or using a sharper filter cut-off. You will anyway, by padding it.
The woofer has a nice, smooth curve up to the 2,500hz recommended lower end of the tweeter. I wouldn't go higher, because of a dip around 3.4KHz and a peak in the woofer's response around 4.6Khz, as the summed response may reveal them and be noticeable. Also, if the tweeter's power rating is tested for a 6db first order crossover @ 2.5KHz (ask PE tech), then you can go with a 12db 2nd order to protect the tweeter. Your system power rating may be around 40-50W per channel. Call the PE tech guys and they can point you in the right direction.
What's the make/ model # of your amp/ receiver?