Just going by the graphics card, notebookcheck.com seems to indicate that the 645m is a little bit stronger than the 7670m.
I couldn't find a comparison with the respective cpu's as well though. Technically, the i7632qm is stronger than the i5 3220m, I just don't know how much stronger. It really depends on what games you will end up playing, but I feel like the i7/7670m combo will be a little better. It will more battery so be prepared to be plugged in more. The i5 is much more power efficient.
Make sure you check the games you'll be playing for whether or not they are more cpu or gpu dependent as well.